[1]奚运涛,刘星辰,黄晓江,等.钛合金材料在石油工业中的应用及其抗腐蚀性能研究进展[J].焊管,2023,46(11):1-8.[doi:10.19291/j.cnki.1001-3938.2023.11.001]
　XI Yuntao,LIU Xingchen,HUANG Xiaojiang,et al.Application and Corrosion Properties of Titanium Alloys in Petroleum Industry[J].,2023,46(11):1-8.[doi:10.19291/j.cnki.1001-3938.2023.11.001]
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钛合金材料在石油工业中的应用及其抗腐蚀性能研究进展()
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《焊管》[ISSN:1001-3938/CN:61-1160/TE]

卷:
46
期数:
2023年第11期
页码:
1-8
栏目:
综述
出版日期:
2023-11-19

文章信息/Info

Title:
Application and Corrosion Properties of Titanium Alloys in Petroleum Industry
文章编号:
10.19291/j.cnki.1001-3938.2023.11.001
作者:
奚运涛; 刘星辰; 黄晓江; 陈亚洲; 胡晓莉; 王雷; 张可人; 胥珊娜; 汲江涛
（1. 西安石油大学材料科学与工程学院，西安 710065； 2. 中油国家石油天然气管材工程技术研究中心有限公司，西安 710018； 3. 中国石油宝鸡石油钢管有限责任公司，陕西 宝鸡 721008； 4. 长庆油田第三采油厂，银川 750006； 5. 长庆油田第十采油厂，甘肃 庆阳 745000； 6. 中铁第一勘查设计院集团有限公司，西安 710043）
Author(s):
XI Yuntao;  LIU Xingchen;  HUANG Xiaojiang;  CHEN Yazhou;  HU Xiaoli;  WANG Lei;  ZHANG Keren;  XU Shanna;  JI Jiangtao
(1. School of Materials Science and Engineering, Xi’an Shiyou University, Xi’an 710065, China; 2. Chinese National Engineering Research Center for Petroleum and Natural Gas Tubular Goods Co., Ltd., Xi’an 710018, China; 3. CNPC Baoji Petroleum Steel Pipe Co., Ltd., Baoji 721008, Shaanxi, China; 4. No. 3 Oil Production Plant of Changqing Oilfield Company, Yinchuan 750006, China; 5. No. 10 Oil Production Plant of Changqing Oilfield Company, Qingyang 745000, Gansu, China; 6. China Railway First Survey and Design Institute Group Co., Ltd., Xi’an 710043, China)
关键词:
钛合金; 油井管; 抗腐蚀性能; 应用
Keywords:
titanium alloy;  oil country tubular goods (OCTG);  corrosion resistance;  application
分类号:
TG146.23
DOI:
10.19291/j.cnki.1001-3938.2023.11.001
文献标志码:
A
摘要:
钛合金材料由于具有高强度、低弹性模量和优良的耐腐蚀性，在石油工业中常被作为油井管的新材料来代替碳钢。从钛合金在油井管中的应用入手，综述了其力学性能和钛合金钻杆、油套管抗腐蚀性能的研究进展，并对比了石油工业中常用的几种碳钢材料与钛合金的疲劳寿命。同时，讨论了添加金属元素与优化制造工艺这两方面因素对钛合金抗腐蚀性能的影响。最后，提出了钛合金在实际生产应用过程中可能面临的问题。
Abstract:
Titanium alloy is often used as a new material to replace carbon steel for oil country tubular goods(OCTG) in petroleum industry because of its high strength, low elastic modulus and excellent corrosion resistance. Starting from the application of titanium alloy in OCTG in petroleum industry, this paper reviews the research progress of its mechanical properties and corrosion properties in titanium alloy drill pipe and oil casing, and compares the fatigue life of several carbon steel materials and titanium alloy commonly used in petroleum industry. At the same time, the effects of adding metal elements and optimizing manufacturing process on corrosion resistance of titanium alloy were discussed. Finally, the possible problems in the actual production and application of titanium alloys are presented.

参考文献/References:

［1］ ZHANG J H，LI X X，XU D S，et al. Recent progress in the simulation of microstructure evolution in titanium alloys［J］.Progress in Natural Science： Materials International，2019，29（3）：295304.［2］ WU D，LIU L B，ZENG L J，et al. Designing high strength titanium alloy using pseudospinodal mechanism through diffusion multiple experiment and CALPHAD calculation［J］. Journal of Materials Science & Technology，2021（74）：7888.［3］ NG C H，BERMINGHAM M J，DARGUSCH M S. Eliminating segregation defects during additive manufacturing of high strength β titanium alloys［J］.Additive Manufacturing，2021（39）：101855.［4］ SHI A，CAI D，HU J，et al. Development of a low elastic modulus and antibacterial Ti13Nb13Zr5Cu titanium alloy by microstructure controlling［J］.Materials Science and Engineering：C，2021（126）：112116.［5］ WEI D B，CHEN X H，ZHANG P Z， et al. Plasma surface tantalum alloying on titanium and its corrosion behavior in sulfuric acid and hydrochloric acid［J］.Applied Surface Science，2018（441）：448457.［6］ PANG J J，BLACKWOOD D J. Corrosion of titanium alloys in high temperature near anaerobic seawater［J］.Corrosion Science，2016（105）：1724.［7］ WEI X， AY A， XIN L A， et al. Synergistic interactions between wear and corrosion of Ti16Mo orthopedic alloy［J］. Journal of Materials Research and Technology，2020（9）：999610003.［8］ MK A， HCC B. Simultaneous improvement of corrosion resistance and bioactivity of a titanium alloy via wet and dry plasma treatments［J］.Journal of Alloys and Compounds，2021（851）：156840.［9］ MAJUMDAR D D，KUMAR V，ROYCHOWDHURY A， et al. In vivo analysis of bone tissue interface in medical grade titanium and porous titanium with and without cenosphere as space holder［J］. Materialia，2020（9）：100623.［10］ MANUEL G， KRYSTIAN M， ROBERT H， et al. Titanium alloy tubing for HPHT application［J］.Social of Petroleum Engineers，2008（11578）：2124.［11］ ZERINGUE R.HPHT completion challenges, SPE high pressure/high temperature sour well design applied technology workshop［J］. The Woodlands TX，2005（3）：1719.［12］ LIU Q，ZHOU B，ZHANG J T，et al. Influence of combined cathode modification on corrosion behavior and passive film characteristics of Ti 6Al 4V Alloy used for oil country tubular goods［J］.Corrosion Science，2022（207）： 110569.［13］ HUANG S，ZHANG J，MA Y， et al. Influence of thermal treatment on element partitioning in titanium alloy［J］.Journal of Alloys and Compounds，2019（791）：575585.［14］ CLEARFIELD H M. Surface preparation of metals［J］.Engineered Materials Handbook，1982（3）：79．［15］ VEIGA C ，DAVIM J P ，LOUREIRO A J R. Properties and applications of titanium alloys： A brief review［J］.Reviews on Advanced Materials Science，2012，32（2）：133148.［16］ PUSHP P，DASHARATH S M，ARATI C. Classification and applications of titanium and its alloys［J］. Materials Today： Proceedings，2022，54（2）：537542.［17］ JAMES A. First commercial application of grade 26 titanium 0.10 ruthenium alloy［J］.NACE Corrosion， 2002（02127）：115．［18］ PER G O，FRODE B，RONALD W S. Prevention of hydrogen damage of offshore titanium alloy components by cathodic protection systems［J］. NACE Corrosion，1997（447）： 914．［19］ BOB H，MANUEL G，KRYSTIAN M，et al. Titanium alloy tubing for HPHT OCTG applications［J］.NACE Corrosion， 2010（10318）：114．［20］ MOU Y S， YU H， LIAN Z H， et al. Experimental and numerical study on mechanical performance of titanium drill pipe in severe doglegs［J］. Unconventional Resources Technology Conference， 2021（208273）： 115.［21］ FENG C，LI R Z，LIU Y G，et al. Aging treatment effect on microstructure and mechanical properties of Ti5Al3V1.5Mo2Zr titanium alloy drill pipe［J］. Journal of Materials Engineering and Performance，2020，10（14）：115.［22］ LIU Q，LI N，SHEN Z X，et al. Calculation model and experimental study of the collapse strength of titanium alloy tubing and casing［J］.Scientific Reports，2022（12）：4526.［23］ SCHUTZ R W，CLAPP G，MEKHA B，et al. Resistance of UNS R56404 titanium to mercury liquid metal embrittlement［C］//NACE International Corrosion，2016（7556）：114.［24］ SCHUTZ R W，JENA B C. Sour service test qualification of a new high strength titanium alloy UNS R55400［C］//NACE International Corrosion，2015（5794）：115.［25］ SHADRAVAN A，AMANI M.HPHT 101What petroleum engineers and geoscientists should know about high pressure high temperature wells environment［J］.Energy Science and Technology，2012，4（2）：36.［26］ ZHANG F F， FENG C， ZHU L J， et al. Research progress on corrosion resistance of titanium alloy oil well tubing［J］. Material Science Forum，2021（1035）：528533.［27］ HU D F，WEI Z H，LIU R B，et al. Enrichment control factors and exploration potential of lacustrine shale oil and gas：A case study of Jurassic in the fulling area of the Sichuan Basin［J］.Natural Gas Industry：B，2022，9（1）：18.［28］ SUN J G，SONG D J. The research and application of titanium alloys for oil and natural gas at home and abroad［J］.Materials Development and Application，2019，34（6）：96102.［29］ CHANDLER B，JELLISON M J，PAYNE M L，et al. Advances and emerging drillstring technologies overcome operational challenges［J］. World Oil，2006（10）：2334.［30］ CRAIG B. Oilfield metallurgy and corrosion［J］. Metcorrosion， 2004（3）：84115.［31］ ZIOMEKMOROZ M. Environmentally assisted cracking of drill pipes in deep drilling oil and natural gas wells［J］. Journal of Materials Engineering and Performance，2012（6）：21.［32］ SCHUTZ R W， WATKINS H B. Recent developments in titanium alloy application in the energy industry［J］. Materials Science and Engineering A，1998（243）：305315.［33］ LIU W Y，BLAWERT C，ZHELUDKEVICH M L. Effects of graphene nanosheets on the ceramic coatings formed on Ti6Al4V alloy drill pipe by plasma electrolytic oxidation［J］.Journal of Alloys and Compounds，2019（789）：9961007.［34］ JACKIE E， SCHUTZ R W， EDMOND I. Development of Titanium Drill Pipe for Short Radius Drilling［J］.Society of Petroleum Engineers，2000（59140）：111.［35］ YUAN W Y，ZHANG Q H. Short radius horizontal well drilling and completion technology for shallow heavy oil sidetracking in Kazakhstan［J］.Oil Technology，2006， 16（3）：13.［36］ HU X H. Titanium alloy drill pipe the best choice for short radius horizontal drilling［J］. China Petroleum Machinery， 2000，28（6）：61.［37］ PENG X B， YU H， LIAN Z H， et al. Material optimization of drill pipe in complex wellbore environments by comparing fatigue life and cost［J］.Energy Reports，2021（7）：50425430.［38］ HARGRAVE B，GONZALEZ M，MASKOS K，et al. Titanium alloy tubing for HPHT OCTG applications［C］.//Corrosion conference and expo 2010，NACE International，2010（10318）： 1.［39］ L V X L，SHU Y，ZHAO G X. Research and application progress of Ti alloy oil country tubular goods［J］. Rare Metal Materials and Engineering，2014，43（6）：15181524.［40］ LIU Q，SONG S Y，LI D J，et al. Application of titanium alloy in petrochemical industry［C］//Proceedings of the international conference on string and tubing of oil and gas wells，Xi an：CNPC，2014：383396.［41］ FU Y R，GU S Q，SONG H M，et al. Application status and prospect of titanium alloy pipe in exploration and development of high sour natural gas［J］.China Petroleum Machinery， 2018，46（3）：116124.［42］ CHEN X W，LIAO D D，ZHANG D F，et al. Effect of content of graphene on corrosion behavior of MicroArc oxidation coating on titanium alloy drill pipe［J］.International Journal of Electrochemical Science，2020（15）：710721.［43］ CHEN X，LIAO D，JIANG X，et al. Effect of tungsten doping on the performance of MAO coatings on a Ti6Al4V drill pipe［J］.Surface Innovations，2020，8（5）：279286.［44］ WANG X Y，ZHU S D，LIU Q，et al. Corrosion behavior on titanium alloys as OCTG in oil fields［J］.Materials Science Forum，2021（1032）：195200.［45］ WANG X Y，ZHU S D，YANG Z G，et al. Corrosion resistance mechanism of TC4 titanium alloy under different stress loading conditions［J］. Materials，2022（15）：4381.［46］ SCHUTZ R W， JENA B C，WALKER H W. Comparing environmental resistance of UNS R55400 alloy tubulars to other oilfield titanium alloys［J］. NACE International Corrosion，2016（7328）：114.［47］ WEI Y，PAN Z M，FU Y，et al. Effect of annealing temperatures on microstructural evolution and corrosion behavior of TiMo titanium alloy in hydrochloric acid［J］. Corrosion Science，2022（197）：110079.［48］ LI R Z，FENG C，JIANG L，et al. Research status and development of titanium alloy drill pipes［J］.Materials Science Forum，2019（944）：903909.［49］ SCHUTZ R W，WATKINS H B. Recent developments in titanium alloy application in the energy industry［J］. Materials Science and Engineering A，1998（243）：305315.［50］ SCHUTZ R W. Performance of ruthenium enhanced ab titanium alloys in aggressive sour gas and geothermal well produced fluid brines［J］. NACE Corrosion， 1997： 32.［51］ SCHUTZ R W， BAXTER C F， BOSTER P L. Applying titanium alloys in drilling and offshore production systems［J］. Journal of metals， 2001， 53（4）： 3335.［52］ ZHANG Y F， LI J Z， CHE S H， et al. Chemical leveling mechanism and oxide film properties of additively manufactured Ti6Al4V alloy［J］.Metals & Corrosion， 2019（54）：1375313766.［53］ ZHANG F Y， DENG Y L， ZHOU X， et al. Effect of C addition on microstructure and mechanical properties of laser microalloying TiAlVC titanium matrix composites［J］. Journal of Materials Research and Technology， 2022（20）： 147156.［54］ ZHAO E T， SUN S C， ZHANG Y. Recent advances in silicon containing high temperature titanium alloys［J］.Journal of Materials Research and Technology， 2021（14）： 30293042.

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备注/Memo

备注/Memo:
收稿日期：2023-06-12基金项目： 国家自然科学基金“CrCoNi中熵合金梯度孪晶结构多角度作用下止裂增韧原理与设计”（项目编号12102340）；陕西高校青年创新团队建设项目（陕教函2023-997-29）；西安石油大学青年科研创新团队建设项目（项目编号2019QNKYCXTD14）。作者简介：奚运涛（1978—）， 山东巨野人，工学博士，教授，硕士生导师。主要研究方向为油气田腐蚀和结垢机理及防治措施研究、材料表面处理技术以及油气田新材料和新工具研发与应用。通讯作者： 王 雷（1988—），陕西西安人，工学博士，教授，硕士生导师。主要研究方向为石油管材力学性能分析、石油设备腐蚀与防护。
更新日期/Last Update: 2023-11-23